Start with the Liouville operator where for any Heisenberg observable
and
This generalizes to both classical mechanics where , a function over the positions and momentum, or quantum mechanics where is a self Hermetian matrix. If the Hamiltonian isn't time dependent, then neither is the Heisenberg Hamiltonian, and thus the Liouville operator won't be time dependent. Then time evolution can just be simplified to
Projection Operator
We want to split the observables into "relevant" and "irrelevant" groups, then split equations of motion of the relevant observables into a part that only depends on the relevant observables and a part that depends on the irrelevant observables. We assume, with minimal assumptions, arbitrary projection operator .
Weird Identity
Let
then
and operators commute with their exponent
And fundamental theorem of calculus
Then left multiply
So
We have
Then use the operator idendity on the right one
more stuff
Projected force
Let the projected force be defined as
Then gives
Note that we didn't make any assumptions about the projection operator or the Liouville operator , so it should work for any projection operator on any time evolution.
Zwanzig Projection Operator
The Zwanzig projection operator can be defined by
Where is the cannonical equilibrium distribution, and is some collection of observables. Let these be called the "relevant" observables. We want to find the time evolution of these relevant observables.
First Term
we can do integration by parts and assume goes to zero at infinity
And so
Then integrate by parts again
Chain rule
Let
Second and Third Term
We probably can't get an exact expression for the second term but we can relate it to the third term.
Looking at just
Next we show that